Comprehensive Organometallic Chemistry III, Volumes 1 - 13
Edited by: Crabtree, Robert H.; Mingos, D. Michael P. © 2007
Elsevier
Description: Presents a comprehensive overview of the major developments in the field since 1993 providing general and significant insights.
Preface
•
Contents of All Volumes
•
Part I. General Introduction
1.01 Classification of Organotransition Metal Compounds
1.02 Ligands, Reagents, and Methods in Organometallic Synthesis
•
Part II. Reaction Types and Mechanisms
1.03 General Classification of Organometallic Reactions
1.04 Reaction Mechanisms of Multistep Catalytic Cycles
1.05 Mechanistic Aspects of Olefin-Polymerization Catalysis
1.06 Metathesis Reactions
•
Part III. Experimental Methods and Techniques
1.07 Experimental Methods and Techniques: Basic Techniques
1.08 Metal Vapor Synthesis: Principles and Practice
1.09 Organometallic Photochemistry, Synthetic Aspects and Applications
1.10 Studying Highly Reactive Organometallic Complexes with Infrared Spectroscopy: Matrix Isolation, Liquefied Noble Gases, Supercritical Fluids, and Time-Resolved IR Spectroscopy
1.11 Organometallic Electrochemistry: Thermodynamics of Metal-Ligand Bonding
1.12 Applications of Sonochemistry and Microwaves in Organometallic Chemistry
1.13 High-Throughput Organometallic Chemistry: Chemical Approaches, Experimental Methods, and Screening Techniques
1.14 Photoelectron Spectroscopy
1.15 Dynamic NMR Spectroscopy in Organometallic Chemistry
1.16 Parahydrogen-Induced Polarization in Organometallic Chemistry
1.17 Solid-State NMR Spectroscopy in Organometallic Chemistry
1.18 High Pressure NMR and IR Spectroscopy in Organometallic Chemistry
1.19 Kinetics Studies
1.20 Isotope-Labeling Studies and Kinetic and Equilibrium Isotope Effects in Organometallic Reactions
•
Part IV. Structure and Bonding in Organometallic Compounds
1.21 Structure and Bonding in Organometallic Compounds: Diffraction Methods
1.22 Structure and Bonding in Organometallic Compounds: Organometallic Thermochemistry
1.23 The Application of Modern Computational Chemistry Methods to Organometallic Systems
1.24 Dihydrogen and other σ Bond Complexes
1.25 Advances in Carbon-Hydrogen Activation
1.26 Transition Metal-Mediated C–F Bond Activation
1.27 Hydrodesulfurization and Hydrodenitrogenation
1.28 Organometallic Chemistry in the Gas Phase
1.29 Organometallic Chemistry in Aqueous and Biphasic Media
1.30 Organometallic Chemistry in Ionic Liquids
1.31 Bioorganometallic Chemistry
Index
•
Volume 2. Compounds of Groups 1 to 2 and 11 to 12
Preface
•
Contents of All Volumes
2.01 Alkali Metal Organometallics - Structure and Bonding
2.02 Alkaline Earth Organometallics
2.03 Copper Organometallics
2.04 Silver Organometallics
2.05 Gold Organometallics
2.06 Zinc Organometallics
2.07 Mercury and Cadmium Organometallics
Index
•
Volume 3. Compounds of Groups 13 to 15
Preface
•
Contents of All Volumes
3.01 Boron-Containing Rings Ligated to Metals
3.02 Polyhedral Carboranes
3.03
s - and
p -Block Heteroboranes and Carboranes
3.04
d - and
f -Block Metallaboranes
3.05 Metallacarboranes of
d - and
f -Block Metals
3.06 Aluminum Organometallics
3.07 Gallium, Indium, and Thallium, Excluding Transition Metal Derivatives
3.08
d -Block Complexes of Aluminum, Gallium, Indium, and Thallium
3.09 Oligosilanes
3.10 Compounds with Bonds between Silicon and
d -Block Metal Atoms
3.11 Organopolysilanes
3.12 Silicones
3.13 Germanium Organometallics
3.14 Tin Organometallics
3.15 Lead Organometallics
3.16 Arsenic, Antimony, and Bismuth Organometallics
Index
•
Volume 4. Compounds of Groups 3 to 4 and the F Elements
Preface
•
Contents of All Volumes
4.01 Complexes of Group 3 and Lanthanide Elements
4.02 Complexes of Actinide Elements
4.03 Complexes of Titanium in Oxidation States 0 to II
4.04 Complexes of Titanium in Oxidation State III
4.05 Complexes of Titanium in Oxidation State IV
4.06 Complexes of Zirconium and Hafnium in Oxidation States 0 to II
4.07 Complexes of Zirconium and Hafnium in Oxidation State III
4.08 Complexes of Zirconium and Hafnium in Oxidation State IV
4.09 Olefin Polymerizations with Group IV Metal Catalysts
Index
•
Volume 5. Compounds of Groups 5 to 7
Preface
•
Contents of All Volumes
5.01 Vanadium Organometallics
5.02 Niobium Organometallics
5.03 Tantalum Organometallics
5.04 Chromium Compounds with CO or Isocyanides
5.05 Chromium Compounds without CO or Isocyanides
5.06 Molybdenum Compounds with CO or Isocyanides
5.07 Molybdenum Compounds without CO or Isonitrile Ligands
5.08 Tungsten Compounds with CO or Isocyanides
5.09 Tungsten Compounds without CO or Isocyanides
5.10 Manganese Compounds with CO Ligands
5.11 Manganese Compounds without CO or Isocyanides
5.12 Technetium Organometallics
5.13 Rhenium Compounds
Index
•
Volume 6. Compounds of Group 8
Preface
•
Contents of All Volumes
•
Part I. Mononuclear Iron Compounds without Hydrocarbon Ligands
6.01 Mononuclear Iron Carbonyls without Hydrocarbon Ligands
•
Part II. Mononuclear Compounds with Hydrocarbon Ligands
6.02 Mononuclear Iron Compounds with η
1 -Hydrocarbon Ligands
6.03 Mononuclear Compounds with Hydrocarbon Ligands: Compounds with η
2 –η
4 Hydrocarbon Ligands
6.04 Mononuclear Compounds with C
5 and C
6 Ligands
6.05 Mononuclear Iron Compounds: Ferrocenes
•
Part III. Dinuclear Iron Compounds
6.06 Dinuclear Iron Compounds with Iron-Iron Bonds
•
Part IV. Iron Cluster Compounds
6.07 Iron Cluster Compounds: Compounds without Hydrocarbon Ligands
6.08 Iron Cluster Compounds: Compounds with Hydrocarbon Ligands
6.09 Iron Cluster Compounds: Compounds with Fe–C Bonds to Heteroatom Ligands
•
Part V. Compounds Containing Bonds between Iron and other Transition Metals
6.10 Heterometallic Iron-Containing Compounds
•
Part VI. Mononuclear Ru/Os Compounds without Hydrocarbon Ligands
6.11 Mononuclear Ru/Os Compounds without Hydrocarbon Ligands
•
Part VII. Mononuclear Ru/Os Compounds with Hydrocarbon Ligands
6.12 Mononuclear Ru/Os Compounds with Hydrocarbon Ligands: Compounds with η
1 -Ligands
6.13 Mononuclear Ru/Os Compounds with Hydrocarbon Ligands: Compounds with η
2 –η
4 Ligands
6.14 Mononuclear Ru/Os Compounds with Cyclic C
5 –C
6 Ligands (except Compounds Containing Monohapto Ligands)
6.15 Mononuclear Ru/Os Compounds with η
1 and C
5 –C
6 Ligands
6.16 Mononuclear Ru/Os Compounds: Ruthenocenes and Osmocenes
•
Part VIII. Dinuclear Ru/Os Compounds
6.17 Dinuclear Ru/Os Compounds with Metal-Metal Bonds
•
Part IX. Trinuclear and other Ru/Os Clusters
6.18 Trinuclear Clusters of Ru/Os without Hydrocarbon Ligands
6.19 Trinuclear Clusters of Ru/Os with Hydrocarbon Ligands
6.20 Trinuclear Ruthenium Clusters with Cyclopentadienyl Ligands
6.21 Trinuclear Ru/Os Clusters Containing Arene Ligands
6.22 Trinuclear Clusters of Ru/Os: Compounds Containing M–C Bonds to Heteroatom Ligands
•
Part X. Tetranuclear Ru/Os Clusters
6.23 Tetranuclear Clusters of Ru/Os
6.24 Medium- and High-Nuclearity Clusters of Ru/Os
6.25 Heterometallic Ru/Os-Containing Compounds
Index
•
Volume 7. Compounds Group 9
Preface
•
Contents of All Volumes
7.01 Cobalt Organometallics
7.02 Rhodium Organometallics
7.03 Application of Rhodium Complexes in Homogeneous Catalysis with Carbon Monoxide
7.04 Iridium Organometallics
7.05 Commercial Applications of Iridium Complexes in Homogeneous Catalysis
Index
•
Volume 8. Compounds of Group 10
Preface
•
Contents of All Volumes
8.01 Nickel Complexes with Carbonyl, Isocyanide, and Carbene Ligands
8.02 Nickel-Carbon σ-Bonded Complexes
8.03 Nickel–Carbon π-Bonded Complexes
8.04 Palladium Complexes with Carbonyl, Isocyanide, and Carbene Ligands
8.05 Palladium-Carbon σ-Bonded Complexes
8.06 Palladium-Carbon π-Bonded Complexes
8.07 Platinum Complexes with Carbonyl, Isocyanide, and Carbene Ligands
8.08 Platinum-Carbon σ-Bonded Complexes
8.09 Platinum–Carbon π-Bonded Complexes
Index
•
Volume 9. Applications I: Main Group Compounds in Organic Synthesis
Preface
•
Contents of All Volumes
9.02 Sodium and Potassium
9.03 Magnesium
9.04 Zinc and Cadmium
9.05 Boron
9.06 Aluminium
9.07 Silicon
9.08 Tin
9.09 Lead
9.10 Antimony and Bismuth
9.11 Selenium
9.12 Copper, Silver, and Gold
9.13 Tellurium
9.14 Indium and Gallium
Index
•
Volume 10. Applications II: Transition Metal Compounds in Organic Synthesis 1
Preface
•
Contents of All Volumes
•
Part I. C–H Bond Formation
10.01 C–H Bond Formation by Asymmetric and Stereoselective Hydrogenation
10.02 C–H Bond Formation: Through Isomerization
•
Part II. Synthetic Reactions via C–H Bond Activation
10.03 Synthetic Reactions via C–H Bond Activation: C–C and C–E Bond Formation
10.04 Synthetic Reactions via C–H Bond Activation: Carbene and Nitrene C–H Insertion
10.05 Synthetic Reactions via C–H Bond Activation: Oxidation of C–H Bonds
•
Part III. C–C Bond Formation (Part 1) by Addition Reactions
10.06 C–C Bond Formation (Part 1) by Addition Reactions: Through Carbometallation Mediated by Group 4–7 Metals
10.07 C–C Bond Formation (Part 1) by Addition Reactions: Through Carbometallation Catalyzed by Group 8–11 Metals
10.08 C–C Bond Formation through Conjugate Addition of C–M to C=C–C=O and C=C–NO
2
10.09 C–C Bond Formation through Addition of C–M to C=O, C=N, and C≡N Bonds
10.10 Metal-Catalyzed Reductive Carbocyclization (C=C, C≡C, C=O Bonds)
10.11 C–C Bond Formation through Reaction of CO
2 with C≡C and C=C–C=C
10.12 C–C Bond Formation (Part 1) by Addition Reactions: Alder-Ene Reaction
10.13 C–C Bond Formation (Part 1) by Addition Reactions: Higher-Order Cycloadditions
•
Part IV. C–O and C–N Bond Formation
10.14 C–O Bond Formation through Transition Metal-Mediated Etherification
10.15 C–N Bond Formation through Amination
•
Part V. C–E Bond Formation (E = Si, Sn, B, Te, S, P)
10.16 C–E Bond Formation through Element-Element Addition to Carbon-Carbon Multiple Bonds
10.17 C–E Bond Formation through Hydrosilylation of Alkynes and Related Reactions
10.18 C–E Bond Formation through Asymmetric Hydrosilylation of Alkenes
10.19 C–E Bond Formation through Hydroboration and Hydroalumination
Index
•
Volume 11. Applications II: Transition Metal Compounds in Organic Synthesis 2
Preface
•
Contents of All Volumes
•
Part I. C–C Bond Formation (Part 2) by Cross-Coupling
11.01 C–C Bond Formation by Cross-Coupling
11.02 Reductive Coupling Reactions Promoted by Low-Valent Early Transition Metals and Lanthanoids
•
Part II. C–C Bond Formation (Part 2) by Substitution Reactions
11.03 C–C Bond Formation (Part 2) by Substitution Reactions: Allylic Alkylation
11.04 C–C Bond Formation (Part 2) by Substitution Reactions: Substitution at Propargylic and Benzylic Positions
•
Part III. Synthetic Reactions of M=C and M=N Bonds
11.05 Synthetic Reactions of M=C and M=N Bonds: Ylide Formation, Rearrangement, and 1,3-Dipolar Cycloaddition
•
Part IV. Metathesis Reactions
11.06 Olefin Cross-Metathesis
11.07 Ring-Closing Olefin Metathesis for Organic Synthesis
11.08 Ene-Yne and Alkyne Metathesis
•
Part V. Simultaneous C–C and other Bond Formation
11.09 Sequential Formation of More than One C–C and other Bonds by Multiple Heck-Type Reactions
11.10 Pauson-Khand Reaction
11.11 Silane-Initiated Carbocyclization Catalyzed by Transition Metal Complexes
11.12 Carbonylative Cross-Coupling and Carbocyclization
11.13 Hydroformylation, other Hydrocarbonylations, and Oxidative Alkoxycarbonylation
11.14 Silylformylation
11.15 Amidocarbonylation, Cyclohydrocarbonylation, and Related Reactions
•
Part VII. Transition Metal Catalysts in Polymer Synthesis
11.16 Polymerization of Acetylenes
11.17 Polymerization of Epoxides
11.18 Ring-Opening Metathesis Polymerization (ROMP)
11.19 Cross-Coupling Polymerization
11.20 Polymerization of Alkenes
Index
•
Volume 12. Applications III: Functional Materials, Environmental and Biological Applications
Preface
•
Contents of All Volumes
12.01 Precursors to Semiconducting Materials
12.02 From Metal-Organic Precursors to Functional Ceramics and Related Nanoscale Materials
12.03 Organometallic Derived Metals, Colloids, and Nanoparticles
12.04 Organometallic Complexes for Optoelectronic Applications
12.05 Metallomesogens
12.06 Organometallic Macromolecular Materials
12.07 Organometallic Magnetic Materials
12.08 Medicinal Organometallic Chemistry
12.09 Organometallic Receptors for Charged and Neutral Guest Species
12.10 Surface Organometallic Chemistry
12.11 Organometallic Crystal Engineering
12.12 Organometallic Compounds in Biosensing
12.13 Environmental and Biological Aspects of Organometallic Compounds
12.14 Polymer-Supported Organometallic Catalysts
12.15 Organometallic Clusters
12.16 Organometallic Inclusion and Intercalation Chemistry
12.17 Green Organometallic Chemistry
Index
Preface
•
Contents of All Volumes
Cumulative Subject Index
Title:
Comprehensive Organometallic Chemistry III, Volumes 1 - 13
Publisher:
Elsevier
Copyright / Pub. Date:
© 2007
ISBN:
978-0-08-044590-8
Electronic ISBN:
978-0-080-45047-6
No. Pages:
10290
Author/Editor:
Edited by: Crabtree, Robert H.; Mingos, D. Michael P.
Knovel Release Date:
May 8, 2008
Knovel Subject Area(s):
Chemistry & Chemical Engineering
Description:
Comprehensive Organometallic Chemistry II provides a valuable and timely update to the earlier Comprehensive Organometallic Chemistry (COC).... Over the past decade, research in organometallic chemistry has increased in popularity, with the volume of primary literature expanding at a very rapid pace. For this reason, review articles are becoming more important in order to allow a researcher to assimilate quickly the scope of a particular area of interest. In this regard, COC II achieves its goals admirably and is an essential addition to any science library.
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